If you require 64 GB total (which would only be necessary with professional workloads, for gaming it won't do anything), then it's better to swap the existing 2x 16 GB for a kit of 2x 32 GB. With four modules, you have twice the stress on the memory system, and then there is the potential problem that you might not be able to get the exact same modules again as your first two are. Then you also have mismatched modules, which provide additional challenges for the memory system, and the speed might not be attainable anymore (as it's only meant for two modules, not four). Also see
RAM explained: Why two modules are better than four / single- vs. dual-rank / stability testing.
The 16 GB DDR5 modules should be single-rank, but that doesn't change the fact that nothing can be guaranteed anymore if you combine two kits of two modules each. And the chance of trouble rises considerably if the new modules are in any way different than the old, in regards to the ICs (memory chips) being used underneath the heatspreader.
Normally, for the RAM amount, you would first try to analyse how much RAM your heaviest workloads need, similar to
here, and then go one step above it. For gaming and daily use, 32 GB total would be more than enough. With 64 GB, more than half of it would just sit there unused and just make things more difficult for the memory system.
Right now, most games run at their maximum performance with 16 GB RAM total already. Yes, you read that right, and it is because even the best gaming consoles only have 16 GB total RAM, and for most games, the console market it very important, so they make sure the games don't need more RAM.
Some games can benefit from a bit more RAM, but with 2x 16 GB those would already be well taken care of too. Then you could go up to 2x 24 GB, because those kits still use single-rank DIMMs, which tend to run better than the 32 GB (and up) dual-rank DDR5 DIMMs.
BTW, the BIOS should be updated to the latest version (very important for your 14th gen CPU). Sometimes, with these pre-built PCs, you can't use the MSI BIOS updates for the retail board, because they might have used a custom BIOS for your board, then you'd have to check with Corsair for updates. And then there's my
Guide: How to set good power limits in the BIOS and reduce the CPU power draw, with which you can improve how the CPU is running.