That makes sense. The 200mm fans probably pull quite a lot of amps, so each one was placed on a separate header for safety. That's good. This means you'll just have to make sure you change Fan 4 and 5 fan profiles to match. You don't have to, but for easy of setup it will make the most sense.
One thing you still need to find out is whether the fans (and your pump) specifications mention anything about PWM. If you're not sure, you can pull the fan cable off the header and see if it is 3 pin (DC) or 4 pin (PWM). Then you're ready to start fan tuning. You first change the Auto setting to PWM or DC based upon the fan's specification, then enable Smart Fan, then set your fan curve. Repeat for each fan. Again, if you're not sure about the Pump, can't find any better info, then don't go lower than 60% PWM or 7.2V DC for when temps are below 40C, i.e. idle temps.
In regards to fan curves, you can re-read the tips in Citay's guide. Remember, if you're a gamer, then most games will run the CPU between 50C and 60C, with peaks of 65C or 70C max. [This is what I see with my RTX3080 when running 1440P. I have found that Far Cry 5 is a great game for tuning temperatures and general CPU stability testing and is often very cheap to buy.] You'll want the fans curves to maintain good levels of fan and Pump RPM in this temperature range - but only as aggressive as they need to be. There is no real advantage to trying to run the CPU below these levels for things like gaming. It's far better to focusing more on the GPU temps, and component temps, even if that means slowing down your CPU AIO a bit. After dialing in the middle range, you can just lower everything for the idle conditions, and reserve the max-RPM (if there's any capacity left) for above 70C or 80C, which would encompass your synthetic stress tests.
I hope that makes sense to you.